Schrodinger Equation for Multi-Electron Atom

  • $r$ dependancy
  • Effective Field
  • Spherical Symmetry

Born-Oppenheimer Approximation

Hartree Approximation

Hartree Product

Mean Field Approximation



Pauli Exclusion Principle




Penetration and Sheilding Effect

Effective Nuclear Charge

Periodicity

Slater’s Rule




Aufbau Principle

Hund’s Rule

　

　

　

Reference
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